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  Environmental Arsenic Exposure:
Health Risks and Geochemical Solutions
 

R Number:  R6941
Contractor:  British Geological Survey - Hydrogeology Group
Dates:         1 July 1996 to 31 October 1999
Geochemical and hydrogeological study of arsenic soil-water-rock interactions in naturally vulnerable hydrogeological settings. Provision of scientific guidelines for aquifer management and development of remediation strategies for improved water quality and community health.



Executive Summary
Objectives

  • to determine the key geochemical and hydrogeological controls on mobility of arsenic in groundwaters and aquifers;
  • to provide information necessary for the identification and targeting of potentially vulnerable aquifers;
  • to provide guidelines for remediation in arsenic-contaminated aquifers;
  • to ameliorate drinking-water quality in vulnerable areas and thereby enable improved community health.
  • Methodology

    Hydrogeochemical investigations in arsenic-affected aquifers in Argentina (La Pampa) and Inner Mongolia (Hohhot Basin) in partnership with Instituto de GeoquRmica, Buenos Aires and Hohhot Antiepidemic and Sanitation Station, Hohhot respectively.

  • Groundwater sampling and chemical analysis to establish water quality and hydrogeochemical controls on element mobility;
  • Porewater and sediment extraction and chemical analysis to determine arsenic distribution between solid and aqueous phases;
  • Hydrogeological investigations;
    Mineralogical investigations;
    Dissemination through information leaflets, reports and articles in refereed literature.
  • Results

    Argentina: investigations in La Pampa Province of central Argentina have highlighted a large range of chemical compositions in groundwaters derived from Quaternary loess silt deposits but with some very high arsenic concentrations (<0.004 to 5.3 mg/L). More than 90% of the groundwaters studied have arsenic concentrations in excess of the WHO recommended limit. Other anion and oxyanion species (e.g. species of F, Se, B, V, Mo) are also present in high concentrations and often well correlated with arsenic. Salinity is also a problem in the area. Remediation of potable supplies derived from such aquifers is extremely difficult because of the combined problems of salinity and toxic trace elements.

    Inner Mongolia: hydrogeochemical investigations of groundwaters in the Huhhot Basin, Inner Mongolia are ongoing.

    Conclusions

    On going work

    Further Information
    List of Publications

    Smedley, P L, Nicolli, HB, Barros, AJ and Tullio, J O. 1998. Origin and mobility of arsenic in groundwater from the Pampean Plain, Argentina. In: Water-Rock Interaction, Proc 9th International Conference on Water-Rock Interaction, Taupo, New Zealand, 1998, eds: Arehart, G B and Hulston, J R. 275-278, Balkema, Rotterdam.

    Follow-up Activities

    An earlier part of the programme involved investigations of arsenic problems in groundwaters of Bangladesh and groundwater sampling was carried out in the western part of the country in February 1997 under this project. Subsequent investigations in Bangladesh are being carried out under a separate DFID-TC programme together with Government of Bangladesh (see the BGS Hydrogeology Group).

    Contact Details for Further Information
    Pauline Smedley
    Hydrogeology Group
    British Geological Survey
    Maclean Building
    Wallingford
    OXON OX10 8BB

    Tel: +44 1491 692319
    Fax: +44 1491 692345
    Email: P.Smedley@bgs.ac.uk